Strained and Reactive Donor/Acceptor‐Supported Metallasilanone
نویسندگان
چکیده
A novel stable donor/acceptor-supported MnI-metallasilanone 3 was synthesized. The intramolecular silanone-MnI interaction induces a highly strained three-membered cyclic structure, leading to an exceptionally high reactivity of as donor/acceptor complex silanone. Indeed, metallasilanone readily reacts with various small molecules such H2 or ethylene gas in mild conditions.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202105526